She played a Bond girl alongside Daniel Craig in Quantum of Solace and he garnered worldwide acclaim as Agent 007 in four films.
And Olga Kurylenko and Pierce Brosnan looked exquisite posing on the red carpet together at The November Man premiere in Hollywood on Wednesday.
The 34-year-old actress beamed in a navy blue Michael Van Der Ham dress that accentuated her curves while her co-star was as dapper as ever in a similarly coloured suit.
Olga’s stylish frock featured a bejeweled pattern design which she teamed with a pair of strappy blue heels.
She wore her brown locks up in a loose bun with smokey eye makeup and a pale pink lipstick.
The Ukrainian beauty – who co-starred with Tom Cruise in Oblivion – took in all the splendour of the gala by bringing along her parents.
Meanwhile Pierce, 61, in Brioni suit, kept it very chic in a blue three piece suit with a white shirt and blue tie.
While the Die Another Day star also took time to pose with his two sons, 17-year-old Dylan and 13-year-old Paris, his wife Keely Shaye Smith was noticeably absent.
Olga and Pierce co-star in The November Man which is a thriller based on the Bill Granger novel There Are No Spies.
Brosnan portrays ex-CIA agent Peter Devereaux, who is lured out of retirement to protect a special witness played by Kurylenko.
The cat-and-mouse suspense film is helmed by Roger Donaldson, who previously worked with Brosnan in the 1997 disaster flick Dante’s Peak.
Co-starring Luke Bracey and Eliza Taylor, the film hits theatres on August 27.